Reaction of 1-methoxyimino-6-nitrohexa-2,4-diene, resulting from the reaction of N-methoxypyridinium iodide with nitromethane.

• 高山 浩明

抄録

Chemical transformations of 1-methoxyimino-6-nitrohexa-2, 4-diene (II), resulted from the reaction of N-methoxypyridinium iodide (I) with nitromethane, were examined in relation to the nitro-aci-nitro prototropy. II reacted with diazomethane to afford methyl 1-methoxyimino-hexa-2, 4-diene-6-acinitronate (III), with acetic anhydride and with benzoyl chloride to give O-acetate and O-benzoate of 1-methoxyimino-hexa-2, 4-diene-6-hydroxamic acid (VI) respectively. The ultraviolet spectra of them were correlated to their structures.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 26 (8), 2575-2578, 1978

  公益社団法人 日本薬学会

キーワード

• UV spectra

詳細情報

• CRID: 1390001204168663040
• NII論文ID: 110003623333
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.26.2575
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/26/8/26_8_2575/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1979093969
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可