Ferric ion catalyzed decomposition of hydrogen peroxide in acetonitrile-water mediums.

• 山本 晴彦

• 武井 仁

• 山本 敏夫

• 木村 道也

抄録

The Fe³⁺-catalyzed decomposition of hydrogen peroxide has been investigated in mediums composed of water and acetonitrile in various ratios. The ratios of the amount of decomposed hydrogen peroxide to that of oxygen evolution are in proportion to the average ratios of acetonitrile concentration to hydrogen peroxide in the low acetonitrile content. It shows that the oxidant produced on the Fe³⁺-catalyzed decomposition of hydrogen peroxide is hydroxyl radical. The linear relationship could not be found in high acetonitrile concentration. The oxidant produced on the Fe³⁺-catalyzed decomposition of hydrogen peroxide in high acetonitrile concentration was discussed in relation to the oxidant (ferryl ion) produced in hemoprotein catalyzed decomposition of hydrogen peroxide.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 27 (3), 789-792, 1979

  公益社団法人 日本薬学会

キーワード

• tris (acetylacetonato) iron (III)

詳細情報

• CRID: 1390001204173376384
• NII論文ID: 110003662249
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.27.789
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/27/3/27_3_789/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1980035684
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可