Isolation and structures of oxaphenalenone dimers from Talaromyces bacillosporus.

• 山崎 幹夫

• 奥山 恵美

抄録

Three new oxaphenalenone dimers, bacillosporins A-C, and one known xanthone carboxylic acid, pinselin, were isolated from a fungus, Talaromyces bacillosporus. Bacillosporin A (1) is an acetyl derivative of B (2). Bacillosporin A was transformed to xenoclauxin (5), a known oxaphenalenone dimer, by 2, 3-dichloro-5, 6-dicyanobenzoquinone (DDQ) oxidation. The hemiketal structure of bacillosporin C (7) was proposed on the basis of the spectral data for the compound itself and the hydrogenolysis product (9).

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 28 (12), 3649-3655, 1980

  公益社団法人 日本薬学会

キーワード

• structure determination

詳細情報

• CRID: 1390282679144611968
• NII論文ID: 110003623892
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.28.3649
• COI: 1:CAS:528:DyaL3MXpvFelsg%3D%3D
• ISSN: 13475223
• ISSN: 00092363
• ISSN: http://id.crossref.org/issn/00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/28/12/28_12_3649/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1982072826
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可