Absorption spectral shift of meso-tetraphenylporphinatocadmium on axial ligation.

• 小沢 俊彦

• 花木 昭

抄録

The effects of axial ligation to meso-tetraphenylporphinatocadmium (CdTPP) were studied in dimethyl sulfoxide (DMSO) or dichloromethane (CH₂Cl₂). Addition of neutral (L) or anionic ligands (X-) to CdTPP caused red shifts in the absorption spectrum. The magnitude of the red shift depended on the charge but not on the strength of the Cdligand bond. Further, a relationship between the ratio ε_α/ε_β and the wavenumber of the Soret band was observed.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 31 (6), 2110-2113, 1983

  公益社団法人 日本薬学会

キーワード

• red shift

詳細情報

• CRID: 1390001204166231552
• NII論文ID: 130003769381
• DOI: 10.1248/cpb.31.2110
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/31/6/31_6_2110/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可