Anodic oxidation of pyrones and coumarins.

• 西山 敦子

• 衛藤 英男

• 井口 正信

• 山村 庄亮

抄録

Triacetic lactone, 4-hydroxycoumarins and 2-chloromethyl-5-hydroxy-4-pyrone were subjected to anodic oxidation in methanol containing LiClO₄ or NaCN to afford the corresponding methoxy or cyano compounds. In basic media, however, bispyrone and biscoumarol were produced from triacetic lactone (4-hydroxy-6-methyl-2-pyrone) and 4-hydroxycoumarin, respectively. The formation processes of these oxidation products are discussed.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 31 (8), 2853-2858, 1983

  公益社団法人 日本薬学会

キーワード

• cyanation

詳細情報

• CRID: 1390001204165262208
• NII論文ID: 130003769424
• DOI: 10.1248/cpb.31.2853
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/31/8/31_8_2853/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可