Facile synthesis of the carbocyclic analogue of .BETA.-ribofuranosylmalonate, new synthon for carbocyclic C-nucleoside formation by retrograde aldol C-C bond fission.

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A new carbocyclic C-nucleoside precursor, the carbocyclic analogue of β-ribofuranosylmalonate, has been synthesized through Diels-Alder addition of cyclopentadiene to dimethyl acetoxymethylene-malonate, followed by retrograde C-C bond fissino under reductive conditions.

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