Magnetic Properties of Rare Earth Copper Intermetallic Compounds, RCu<SUB>2</SUB>. I. Heavy Rare Earth.

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Measurements of magnetization and susceptibility have been made on single crystals of heavy rare earth copper compounds, RCu2. All these compounds show metamagnetism with a relative low critical field at 4.2 K. The paramagnetic Curie temperatures along each principal axis are anisotropic. The crystal field parameters V20 and V22 are determined from the values of anisotropic paramagnetic Curie temperatures on the basis of the molecular field theory. These values are in agreement with those evaluated from a point charge model. The neutron diffraction measurements on a TbCu2 single crystal confirm the collinear magnetic structure.

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