Revised structure for the product from the reaction of 3-hydrazinocarbonylmethylene-2-oxo-1,2,3,4-tetrahydroquinoxaline with nitrous acid.

抄録

The structure of the compound 2, 2, 4-dioxo-3-nitroso-1, 2, 4, 5-tetrahydropyrazolo [1, 5-a]-quinoxaline, which was previously obtained from the reaction of 3-hydrazinocarbonyl-methylene-2-oxo-1, 2, 3, 4-tetrahydroquinoxaline (1a) with an excess of nitrous acid, was revised to 3-(1, 2, 4-oxadiazolin-5-on-3-yl)-2-oxo-1, 2-dihydroquinoxaline (7) on the basis of comparison with an authentic sample prepared from 3-cyano-2-oxo-1, 2-dihydroquinoxaline (8) via an unambiguous route.

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