ヒドロキシフェニルビグアニドと塩化メタクリロイルとの反応に関する研究　第１報　フェノール性水酸基をもつイソプロペニル‐１，３，５‐トリアジンの合成と重合

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タイトル別名
  • Studies on the reaction of hydroxyphenylbiguanide and methacryloyl chloride. I. Synthesis and polymerization of isopropenyl-1,3,5-triazines containing a phenolic group.
  • フェノールセイ スイサンキ オ モツ イソプロペニル 1 3 5 トリアジン

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抄録

2-Amino-4- (p- [3] or m- [4] methacryloyloxyanilino) -6-isopropeny1-1, 3, 5-triazines were prepared from the reaction of p- or m-hydroxyphenylbiguanide with twice equivalents of methacryloyl chloride. Treatment of [3] or [4] with phenylbiguanide afforded new triazine monomers containing phenolic function, e. g., 2-amino-4- (p- [1] or m- [2] hydroxyanilino) -6-isopropenyi-1, 3, 5-triazines. The hydrochlorides ([5] and [6]) of [1] and [2] were also obtained in the process of isolation of [1] or [2]. A new azo-dye monomer, 2- amino-4- (3-hydroxy-4-phenylazoanilino) -6- isopropeny1-1, 3, 5-triazine [7] was prepared by the coupling reaction of [2] with benzenediazonium chloride. The homopolymerizations and copolymerizations of [1], [2], [5], [6], and [7] with styrene and methyl methacrylate (M1) were carried out in dimethyl sulfoxide using azobisisobutyronitrile as the initiator. The copolymerization parameters (r1, r2, Q and e) were determined.

収録刊行物

  • 高分子論文集

    高分子論文集 46 (12), 775-781, 1989

    公益社団法人 高分子学会

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