ヒドロキシフェニルビグアニドと塩化メタクリロイルとの反応に関する研究　第２報　メタクリル酸（ｍ‐ビグアニジノフェニル）の合成と重合

DOI Web Site

書誌事項

タイトル別名
  • Studies on the reaction of hydroxyphenylbiguanide and methacryloyl chloride II. Synthesis and polymerization of m-Biguanidinophenyl methacrylate hydrochloride.
  • メタクリルサン m ビグアニジノフェニル ノ ゴウセイ ト ジュウゴウ

この論文をさがす

抄録

m-Biguanidinophenyl methacrylate hydrochloride (mBPMHCl) was synthesized by the reaction of m-hydroxy-phenylbiguanide with a half amount of methacryloyl chloride. 2-Amino-4- (m-methacryloyloxyanilino) -6-isopropeny1-1, 3, 5-triazine was prepared by the neutralization of mBPMHCl with sodium hydroxide. The polymerization and copolymerizations of mBPMHCl (M2) with styrene and methyl methacrylate (M1) were carried out in dimethyl sulfoxide using azobisisobutyronitrile as the initiator. The homopolymer of mBPMHCl was soluble in water and methanol and behaved as an amphoteric polyelectrolyte in water. The copolymerization parameters of mBPMHCl (M2) are as follows. r1=0.22, r2=0.18, Q=1.09, and e=0.99 for St; r1=0.76, r2=0.23, Q=1.65, and e=1.72 for MMA.

収録刊行物

  • 高分子論文集

    高分子論文集 46 (12), 783-787, 1989

    公益社団法人 高分子学会

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ