２‐アミノ‐４‐（ｐ‐アルキルオキシアニリノ）‐６‐イソプロペニル‐１，３，５‐トリアジンの合成と重合

DOI Web Site 被引用文献3件

書誌事項

タイトル別名
  • Synthesis and polymerization of 2-amino-4-(p-alkyloxyanilino)-6-isopropenyl-1,3,5-triazines.
  • 2 アミノ 4 p アルキルオキシアニリノ 6 イソプロペニル 1 3 5 ト

この論文をさがす

抄録

2-Amino-4- (p-alkyloxyanilino) -6-isopropenyl-1, 3, 5-triazines (pCnIT, where “n” means the number of alkyl carbon atoms) were prepared by the reaction of p-alkyloxyphenylbiguanide with methacryloyl chloride for pC4IT, pC6IT, and pC8IT or by the reaction of 2-amino-4- (p-hydroxyanilino) -6-isopropenyl-1, 3, 5-triazine with alkyl bromides for pC10IT-pC18IT. New comb-like polymers were prepared by the homopolymerizations and copolymerizations of pCnIT with styrene, methyl methacrylate, and methyl acrylate (M1) in dimethyl sulfoxide using azobisisobutyronitrile as the initiator. The copolymerization parameters (r1, r2, Q, and e values) were determined. Glass transition temperatures of poly-pC6IT-poly-pC18IT were 192-196°C. The long alkyl side chains of poly-pC12IT-poly-pC18IT can crystallize at around 0°C.

収録刊行物

  • 高分子論文集

    高分子論文集 47 (1), 33-40, 1990

    公益社団法人 高分子学会

被引用文献 (3)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ