Cyclic Voltammetric Characteristics of Tri- and Diarylcarbenium Salts Having Some Methoxyphenyl Groups

• Tatsuo Erabi

  Department of Materials Science, Faculty of Engineering, Tottori University

• Takayuki Ohtsuki

  Department of Materials Science, Faculty of Engineering, Tottori University

• Eiko Osaki

  Department of Materials Science, Faculty of Engineering, Tottori University

• Nobuyuki Tomita

  Department of Materials Science, Faculty of Engineering, Tottori University

• Masahiro Asahara

  Department of Materials Science, Faculty of Engineering, Tottori University

• Masanori Wada

  Department of Materials Science, Faculty of Engineering, Tottori University

抄録

Triarylcarbenium salts (Φa3C+, ΦaΦb2C+, Φb3C+, ΦfΦb2C+, ΦeΦb2C+, PhΦb2C+, and FcC+ΦbPh [Φa, Φb, Φe, Φf, Ph, Fc = 2,4,6-(MeO)3C6H2, 2,6-(MeO)2C6H3, 2-(MeO)C6H4, 4-(MeO)C6H4, C6H5, Fe(η5-C5H5)(η5-C5H4)]) showed a reversible redox wave with one-electron transfer at a Pt electrode in 1,2-dichloroethane, while the reduction of diarylcarbenium salts (Φa2C+H, FcC+ΦaH, FcC+ΦbH, FcC+ΦcH, FcC+ΦeH, and FcC+PhH [Φc = 2,5-(MeO)2C6H3]) proceeded irreversibly. A wide range of cathodic shifts in the redox potentials (198—-377 mV for triarylcarbenium salts) and in the reduction peak potentials (-23—-311 mV for monoaryl(ferrocenyl)carbenium salts) could be observed as the number of o- and p-methoxy groups increased. Probably, the electron donation from the o- and p-methoxy substituents to the central carbon caused the wide negative shift in the redox potentials. These triarylcarbenium salts again showed reversible redox waves in their relatively low concentration region at an ITO electrode in an aqueous acidic medium. In the higher concentration region, an anodic wave was varied to a sharp peak, indicating the adsorption of triarylmethyl radicals. It is very interesting that the reversible redox behavior of these triarylcarbenium salts was observable even in an aqueous medium.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 73 (10), 2237-2242, 2000-10-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644034813824
• NII論文ID: 130004058297
• DOI: 10.1246/bcsj.73.2237
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/73/10/2237/56201085/bcsj.73.2237.pdf
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