Synthesis of <i>β</i>-Hydroxy Nitriles via Indium-Induced Coupling of Bromoacetonitrile with Carbonyl Compounds
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- Shuki Araki
- Department of Applied Chemistry, Nagoya Institute of TechnologyGokiso-cho, Showa-ku, Nagoya 466
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- Masafumi Yamada
- Department of Applied Chemistry, Nagoya Institute of TechnologyGokiso-cho, Showa-ku, Nagoya 466
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- Yasuo Butsugan
- Department of Applied Chemistry, Nagoya Institute of TechnologyGokiso-cho, Showa-ku, Nagoya 466
抄録
<jats:title>Abstract</jats:title> <jats:p>The organoindium reagent, derived from indium metal and bromoacetonitrile, reacted with carbonyl compounds in the presence of chlorotrimethylsilane to give, after hydrolysis, β-hydroxy nitriles. The coupling proceeded with high chemoselectivity, though the diastereoselectivity was low.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 67 (4), 1126-1129, 1994-04-01
Oxford University Press (OUP)
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キーワード
詳細情報
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- CRID
- 1360002219103986816
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- NII論文ID
- 130004148671
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- ISSN
- 13480634
- 00092673
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- データソース種別
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