Sensitization of NaMO3 (M: Nb and Ta) Photocatalysts with Wide Band Gaps to Visible Light by Ir Doping
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- Akihide Iwase
- Department of Applied Chemistry, Faculty of Science, Tokyo University of Science
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- Kenji Saito
- Department of Applied Chemistry, Faculty of Science, Tokyo University of Science
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- Akihiko Kudo
- Department of Applied Chemistry, Faculty of Science, Tokyo University of Science
抄録
<jats:title>Abstract</jats:title> <jats:p>NiO/NaNbO3 (BG: 3.5 eV) showed photocatalytic activity for water splitting into H2 and O2 under UV irradiation. When NaMO3 (M: Nb and Ta) was codoped with iridium ions and alkaline earth metal ions or lanthanum ions, a new visible-light absorption band was observed in addition to the band gap absorption band of the host material. The codopants of alkaline earth metal and lanthanum ions contributed to maintaining the charge balance and forming of fine crystals of the NaMO3 powder. These NaNbO3 and NaTaO3 codoped with iridium ions and alkaline earth metal ions or lanthanum ions showed photocatalytic activities for H2 or O2 evolution from an aqueous solution containing a sacrificial reagent under visible light irradiation.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 82 (4), 514-518, 2009-04
Oxford University Press (OUP)
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キーワード
詳細情報 詳細情報について
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- CRID
- 1360283694082027264
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- NII論文ID
- 130004152584
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- ISSN
- 13480634
- 00092673
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- データソース種別
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