写真用有機化合物の進歩　カプラーの反応性を予測する分子軌道パラメータの検討

DOI

書誌事項

タイトル別名
  • Recent Advances in Organic Compounds for Photographic Materials. A Study of MO Parameters Predicting the Reactivity of Color Couplers for Photographic Materials.

抄録

MO parameters were analyzed in order to predict the reactivity of color couplers for photographic materials. Four kinds of MO parameters for 1-phenyl-5-pyrazolone coupler anions were calculated using AM1/COSMO method. The charge, HOMO energy and absolute hardness showed low correlation coefficients between the reactivity (log kl). The correlation between local electron-donating strength and log ki was good. A similar relationships were found for naphthol couplers.

収録刊行物

キーワード

詳細情報 詳細情報について

  • CRID
    1390001206570068480
  • NII論文ID
    130004284176
  • DOI
    10.11454/photogrst1964.58.466
  • ISSN
    18845932
    03695662
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

問題の指摘

ページトップへ