2元CCDセンサを搭載した開光路型分光計と多重微分スペクトル法を用いた大気中気体成分濃度の測定

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タイトル別名
  • Determination of Atmospheric Constituents Using Open Light Path Spectrometer Equipped with a 2D CCD and Multiderivative Spectra Procedures.
  • 2ゲン CCD センサ オ トウサイ シタ カイコウロガタ ブンコウケイ ト タジュウ ビブン スペクトルホウ オ モチイタ タイキ チュウ キタイ セイブン ノウド ノ ソクテイ

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抄録

An analytical procedure to which the multiderivatives of the atmospheric absorption spectrum and of absorption cross section spectra are applied has been proposed in order to retrieve atmospheric constituent concentrations. In this study, the proposed method was evaluated by applying it to real atmospheric absorption spectra. Preceding the evaluation, an open light path spectrometer for acquiring atmospheric absorption spectra was developed. The instrument consisted of an artificial light source, a telescope for both emitting and receiving light, a reflector, and a spectrometer. Absorption spectra can be acquired in the spectral region from UV to visible. The instrument can achieve a high signal to noise ratio and high-speed sampling because it is equipped with a two-dimensional CCD detector. To evaluate the applicability of the proposed procedure, measurements of concentrations of NO2, O3, SO2, and HCHO were carried out together with other instruments. The results of the comparisons showed good agreement for all species.

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