Photocatalytic Asymmetric Reduction of 3-Methyl-2-oxobutanoic Acid with Chiral Rh(I) Complexes and Powdery Semiconductors

• Hanhein Wang

  Institute of Photographic Chemistry, Academia Sinica

• Tadayoshi Sakata

  Institute for Molecular Science

• Masashi Azuma

  Institute for Molecular Science

• Tetsuo Ohta

  Institute for Molecular Science

• Hidemasa Takaya

  Department of Industrial Chemistry, Faculty of Engineering, Kyoto University

抄録

Photocatalytic asymmetric reduction of 3-methyl-2-oxobutanoic acid giving 2-hydroxy-3-methylbutanoic acid has been carried out in up to 60% ee in aqueous methanol with chiral BINAP–Rh(I) complexes and semiconductor photocatalysts, TiO2 or CdS.

収録刊行物

• Chemistry Letters

  Chemistry Letters 19 (8), 1331-1334, 1990-08-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219108267392
• NII論文ID: 130004417988
• DOI: 10.1246/cl.1990.1331
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/19/8/1331/56059667/cl.1990.1331.pdf
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