Chain and Discrete Dimer Complexes of Molybdenum(II) Trifluoroacetate Axially Coordinated by <i>p</i>-Quinones, [Mo2(O2CCF3)4(2,6-Me-BQ)]<i>n</i> (2,6-Me-BQ = 2,6-dimethyl-<i>p</i>-benzoquinone) and [Mo2(O2CCF3)4(2,6-<i>t</i>-Bu-BQ)2] (2,6-<i>t</i>-Bu-BQ = 2,6-di-<i>t</i>-butyl-<i>p</i>-benzoquinone)

• Makoto Handa

  Department of Chemistry, Faculty of Science, Shimane University

• Hiroki Matsumoto

  Department of Chemistry, Faculty of Science, Shimane University

• Toshihiro Namura

  Department of Chemistry, Faculty of Science, Shimane University

• Tamie Nagaoka

  Department of Chemistry, Faculty of Science, Shimane University

• Kuninobu Kasuga

  Department of Chemistry, Faculty of Science, Shimane University

• Masahiro Mikuriya

  Department of Chemistry, School of Science, Kwansei Gakuin University

• Takanori Kotera

  Department of Chemistry, School of Science, Kwansei Gakuin University

• Ryoji Nukada

  Department of Chemistry, School of Science, Kwansei Gakuin University

抄録

A chain complex [Mo2(O2CCF3)4(2,6-Me-BQ)]n (2,6-Me-BQ = 2,6-dimethylbenzoquinone) and a bis p-quinone adduct complex [Mo2(O2CCF3)4(2,6-t-Bu-BQ)2] (2,6-t-Bu-BQ = 2,6-di-t-butyl-p-benzoquinone) have been prepared and characterized by X-ray crystal structure analyses, 13C-NMR spectrum, and cyclic voltammetry. The effect of alkyl groups R (= Me, t-Bu) at the 2,6-positions of the p-benzoquinone on the structures of the complexes have been discussed.

収録刊行物

• Chemistry Letters

  Chemistry Letters 24 (10), 903-904, 1995-10-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219109123840
• NII論文ID: 130004419641
• DOI: 10.1246/cl.1995.903
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/24/10/903/56069407/cl.1995.903.pdf
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