Molecular Assembly of BChl <i>a</i> Complexes onto ITO Electrode Using Synthetic Light-harvesting Model Polypeptides Bearing Spermine Derivative

• Tsuyoshi Ochiai

  Materials Science and Engineering, Nagoya Institute of Technology

• Mitsuhiro Ota

  Materials Science and Engineering, Nagoya Institute of Technology

• Takahide Asaoka

  Materials Science and Engineering, Nagoya Institute of Technology

• Tomoya Kato

  Materials Science and Engineering, Nagoya Institute of Technology

• Shinichiro Osaka

  Materials Science and Engineering, Nagoya Institute of Technology

• Takehisa Dewa

  Materials Science and Engineering, Nagoya Institute of Technology

• Keiji Yamashita

  Materials Science and Engineering, Nagoya Institute of Technology

• Hideki Hashimoto

  Department of Physics, Graduate School of Science, Osaka City University

• Mamoru Nango

  Materials Science and Engineering, Nagoya Institute of Technology

抄録

1α-Helix hydrophobic polypeptide bearing spermine, which has similar amino acid sequences to the hydrophobic core in the native photosynthetic light-harvesting (LH) 1-α polypeptide from Rhodospirillum (Rsp.) rubrum, was synthesized. Interestingly, an enhanced photoelectric current was observed when BChl a complexes together with the LH1-α model polypeptide were assembled onto an ITO electrode.

収録刊行物

• Chemistry Letters

  Chemistry Letters 37 (1), 98-99, 2007-12-15

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644041342080
• NII論文ID: 130004424899
• DOI: 10.1246/cl.2008.98
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/37/1/98/55597233/cl.2008.98.pdf
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