Ultrastrong Gravity-induced Unusual Reactivity in Radical Addition of Bromotrichloromethane to Ethyl Cinnamate

• Yasuyuki Abe

  Department of Applied Chemistry and Biochemistry, Kumamoto University

• Tsuyoshi Sawada

  Department of Applied Chemistry and Biochemistry, Kumamoto University

• Makoto Takafuji

  Department of Applied Chemistry and Biochemistry, Kumamoto University

• Tsutomu Mashimo

  Shock Wave and Condensed Matter Research Center, Kumamoto University

• Masao Ono

  Advanced Science Research Center, Japan Atomic Energy Agency

• Hirotaka Ihara

  Department of Applied Chemistry and Biochemistry, Kumamoto University

抄録

Radical addition of bromotrichloromethane to ethyl cinnamate was carried out under an ultrastrong gravitational field (>2.5 × 105 G), and ethyl 3-chloro-3-phenyl-2-(trichloromethyl)propionate (A), ethyl 3-bromo-3-phenyl-2-(trichloromethyl)propionate (B), and ethyl 2-bromo-3-phenyl-3-(trichloromethyl)propionate (C) were isolated by reversed-phase HPLC. To date, there has been no report of the synthesis of A and C at 1 G, and this would be the first example of a selectivity change induced by ultrastrong gravity.

収録刊行物

• Chemistry Letters

  Chemistry Letters 39 (3), 174-175, 2010-01-30

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694088095360
• NII論文ID: 130004425778
• DOI: 10.1246/cl.2010.174
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/39/3/174/55601602/cl.2010.174.pdf
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