Lewis Acid-mediated ArSE Aroylation of Naphthalene Derivative: Distinct Second Aroylation Behavior of α-Naphthyl Ketone

DOI PDF 被引用文献11件 参考文献17件
  • Akiko Okamoto
    Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology
  • Ryosuke Mitsui
    Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology
  • Hideaki Oike
    Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology
  • Noriyuki Yonezawa
    Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology

抄録

<jats:title>Abstract</jats:title> <jats:p>Dual ArSE aroylation of 2,7-dimethoxynaphthalene proceeds with distinct susceptibility and regioselectivity depending on the Lewis acid. The TiCl4-mediated reaction readily affords 1,8-diaroylated product. In the AlCl3-mediated reaction, monoaroylation essentially proceeds with partial ether cleavage and under some specific conditions 1,6-diaroylation proceeds in preference to 1,8-diaroylation.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 40 (11), 1283-1284, 2011-10-22

    Oxford University Press (OUP)

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