Geometric Selectivity, Hydrogen-Bonding Interaction, and Solvatochromism of Bis{<i>N</i>-(aminoalkyl)salicylamidato(2−)}cobaltate(III)

• Ryoji Mitsuhashi

  Department of Chemistry, Faculty of Science, Okayama University

• Takayoshi Suzuki

  Department of Chemistry, Faculty of Science, Okayama University

• Yukinari Sunatsuki

  Department of Chemistry, Faculty of Science, Okayama University

• Masaaki Kojima

  Department of Chemistry, Faculty of Science, Okayama University

抄録

Cobalt(III) complexes with N-(aminoalkyl)salicylamide dianions, Ln2− (n = 1–4), have been prepared and their molecular and crystal structures have been determined. The geometric (mer- or fac-) selectivity of [Co(Ln)2]− complexes was dependent on the number of the amine–amidato chelate ring member. Intermolecular homochiral hydrogen-bonds and solvatochromic behavior of the complexes were also observed.

収録刊行物

• Chemistry Letters

  Chemistry Letters 40 (7), 696-698, 2011-06-04

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219111569408
• NII論文ID: 130004426261
• DOI: 10.1246/cl.2011.696
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/40/7/696/55604250/cl.2011.696.pdf
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