Microstructure and Dielectric Properties of Barium Titanate Film Prepared by MOCVD

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Barium titanate (BaTiO3) films were prepared on (100)Pt/(100)MgO substrates by metal-organic chemical vapor deposition (MOCVD). The effects of deposition temperature (Tdep) and O2 partial pressure (PO<SUB>2</SUB>) on the microstructure and dielectric properties of the films were investigated. The BaTiO3 films prepared at Tdep=873 K showed a randomly orientated granular structure, while those prepared at Tdep=973 K showed a significant (001) orientation with a columnar structure. The grain size was strongly affected by PO<SUB>2</SUB> and showed the maximum at PO<SUB>2</SUB>=66 to 93 Pa. The dielectric constant increased from 93 to 640 with increasing grain size from 20 to 130 nm, showing a broad peak at 350 to 380 K.

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  • MATERIALS TRANSACTIONS

    MATERIALS TRANSACTIONS 43 (11), 2880-2884, 2002

    公益社団法人 日本金属学会

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