Synthesis and X-ray Crystallographic Analysis of 1,4-dihydropyridine Photodimerization
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- Zhu Xiaohe
- College of Life Science and Bio-engineering, Beijing University of Technology
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- Ni Chengliang
- College of Life Science and Bio-engineering, Beijing University of Technology
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- Yan Hoong
- College of Life Science and Bio-engineering, Beijing University of Technology
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- Zhong Rugong
- College of Life Science and Bio-engineering, Beijing University of Technology
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抄録
1,4-dihydropyridine undergoes a head-to-tail [2+2] photodimerization that leads to the formation of anti-dimer, syn-dimer and cage dimer in solution. Their crystal X-ray crystallographic analysis suggests that the stereoisomers in solution are restrainted by the relative position of double bonds of intramolecules, hydrogen bonds and steric hindrances, which are different in the solid state. The cage dimer is formed by the intramolecular reaction of syn-dimer, and is topochemical controlled by the nearest distance between potentially reacting double bonds, rotational angles of the building cyclobutane ring and the orientation of carbonyl ester.
収録刊行物
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 22 (3), 379-384, 2009
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詳細情報 詳細情報について
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- CRID
- 1390001204323709056
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- NII論文ID
- 130004464745
- 40016635449
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- NII書誌ID
- AA11576862
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- COI
- 1:CAS:528:DC%2BD1MXoslCitrY%3D
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- ISSN
- 13496336
- 09149244
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- NDL書誌ID
- 10270577
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可