Crystal Structure of <i>N</i>-Methyl-<i>N</i>-phenyl-1,10-phenanthroline-2-carboxamide

DOI Web Site 被引用文献1件
  • KOBAYASHI T.
    Actinide Coordination Chemistry Group, Quantum Beam Science Directorate, Japan Atomic Energy Agency
  • SUZUKI S.
    Actinide Coordination Chemistry Group, Quantum Beam Science Directorate, Japan Atomic Energy Agency
  • SHIWAKU H.
    Actinide Coordination Chemistry Group, Quantum Beam Science Directorate, Japan Atomic Energy Agency
  • YAITA T.
    Actinide Coordination Chemistry Group, Quantum Beam Science Directorate, Japan Atomic Energy Agency

抄録

The single-crystal structure of N-methyl-N-phenyl-1,10-phenanthroline-2-carboxamide, MePhPTA, which is a promising ligand for the effective disposal of high-level radioactive waste, was determined by X-ray crystallography. The structure was solved by a direct method, and refined to R = 0.040. The oxygen atom of the amide group is oriented to the same side of the nitrogen atoms of the phenanthroline moiety. This conformation would be advantageous on metal coordination as a tridentate ligand with one oxygen on an amide group and two nitrogens on the phenanthroline moiety.

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