High-Rate Capability of Lithium-Rich Layered Li₁.₂Ni₀.₁₈Mn₀.₅₉Co₀.₀₃O₂ Cathode Material Prepared from Size-Regulated Precursor Fine Particles

  • KANEKO Shingo
    Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of Chemical Power Sources, Soochow University Research Institute for Engineering, Kanagawa University
  • XIA Bingbo
    Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of Chemical Power Sources, Soochow University
  • ZHANG Qian
    Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of Chemical Power Sources, Soochow University
  • FANG Guoqing
    Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of Chemical Power Sources, Soochow University
  • LIU Weiwei
    Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of Chemical Power Sources, Soochow University
  • SUN Hongdan
    Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of Chemical Power Sources, Soochow University
  • MATSUMOTO Futoshi
    Department of Material and Life Chemistry, Faculty of Engineering, Kanagawa University
  • SATO Yuichi
    Research Institute for Engineering, Kanagawa University
  • ZHENG Junwei
    Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of Chemical Power Sources, Soochow University
  • LI Decheng
    Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of Chemical Power Sources, Soochow University

書誌事項

タイトル別名
  • High-Rate Capability of Lithium-Rich Layered Li<sub>1.2</sub>Ni<sub>0.18</sub>Mn<sub>0.59</sub>Co<sub>0.03</sub>O<sub>2</sub> Cathode Material Prepared from Size-Regulated Precursor Fine Particles

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抄録

A lithium-rich layered cathode material, Li1.2Ni0.18Mn0.59Co0.03O2, was synthesized from size-regulated precursor nanoparticles, which were prepared by a reverse microemulsion technique. The resulting material demonstrated a good cycle stability (50th cycle discharge capacity: 281 mAh g−1 at 20 mA g−1) without any additional modifications or treatments and a high capacity retention (52%) even at 640 mA g−1 compared to the one (5% at 640 mA g−1) obtained via a spray-drying synthesis as a reference. This article is the first report of trying to synthesize a lithium-rich layered cathode material having a high rate capability by controlling the morphology and homogeneity of the precursor particles based on a reverse microemulsion technique.

収録刊行物

  • Electrochemistry

    Electrochemistry 82 (6), 438-443, 2014

    公益社団法人 電気化学会

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