<b>Ring-Opening Polymerization of Glycidyl Phenyl Ether Initiated by Tetra </b><i>n</i><b>-butylammonium Halides as Metal-Free Initiators and Application of Its Polymer System to Networked Polymers </b>

DOI
  • Morinaga Hisatoyo
    Department of Materials Science and Engineering, Kochi National College of Technology
  • Matsumoto Asami
    Department of Materials Science and Engineering, Kochi National College of Technology
  • Matsuda Tsukasa
    Department of Materials Science and Engineering, Kochi National College of Technology
  • Nagai Daisuke
    Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University
  • Endo Takeshi
    Department of Materials Science and Engineering, Kochi National College of Technology Molecular Engineering Institute, Kinki University

抄録

The ring-opening polymerization of glycidyl phenyl ether (GPE) and an epoxy curing reaction of bisphenol A diglycidyl ether (BADGE) were performed with metal-free tetra-n-butylammonium halides (TBAX); the anions included fluoride, chloride, bromide, and iodide. We compared the extent of polymerization achieved as a result of using different TBAX as initiators. The comparison revealed that tetra-n-butylammonium fluoride (TBAF) was the most efficient initiator for both the polymerization of GPE and the epoxy curing reaction of BADGE.

収録刊行物

詳細情報 詳細情報について

  • CRID
    1390282680438138752
  • NII論文ID
    130004648239
  • DOI
    10.11364/networkpolymer.31.272
  • COI
    1:CAS:528:DC%2BC3cXhsF2itbvI
  • ISSN
    2186537X
    13420577
  • 本文言語コード
    en
  • データソース種別
    • JaLC
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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