<b>Ring-Opening Polymerization of Glycidyl Phenyl Ether Initiated by Tetra </b><i>n</i><b>-butylammonium Halides as Metal-Free Initiators and Application of Its Polymer System to Networked Polymers </b>
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- Morinaga Hisatoyo
- Department of Materials Science and Engineering, Kochi National College of Technology
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- Matsumoto Asami
- Department of Materials Science and Engineering, Kochi National College of Technology
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- Matsuda Tsukasa
- Department of Materials Science and Engineering, Kochi National College of Technology
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- Nagai Daisuke
- Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University
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- Endo Takeshi
- Department of Materials Science and Engineering, Kochi National College of Technology Molecular Engineering Institute, Kinki University
抄録
The ring-opening polymerization of glycidyl phenyl ether (GPE) and an epoxy curing reaction of bisphenol A diglycidyl ether (BADGE) were performed with metal-free tetra-n-butylammonium halides (TBAX); the anions included fluoride, chloride, bromide, and iodide. We compared the extent of polymerization achieved as a result of using different TBAX as initiators. The comparison revealed that tetra-n-butylammonium fluoride (TBAF) was the most efficient initiator for both the polymerization of GPE and the epoxy curing reaction of BADGE.
収録刊行物
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- Journal of Network Polymer,Japan
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Journal of Network Polymer,Japan 31 (6), 272-277, 2010
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詳細情報 詳細情報について
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- CRID
- 1390282680438138752
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- NII論文ID
- 130004648239
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- COI
- 1:CAS:528:DC%2BC3cXhsF2itbvI
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- ISSN
- 2186537X
- 13420577
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可