Organic Solar Cells Based on PTB7:PC₇₁BM with Cs₂CO₃ as a Cathode Buffer Layer
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- Kaneto Daichi
- Department of Precision Machinery Engineering, College of Science and Technology, Nihon University
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- Yanagidate Tatsuki
- Department of Precision Machinery Engineering, College of Science and Technology, Nihon University
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- Yanagi Yuichiro
- Department of Precision Machinery Engineering, College of Science and Technology, Nihon University
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- Fujii Shunjiro
- Department of Precision Machinery Engineering, College of Science and Technology, Nihon University
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- Kataura Hiromichi
- Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)
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- Nishioka Yasushiro
- Department of Precision Machinery Engineering, College of Science and Technology, Nihon University
書誌事項
- タイトル別名
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- Organic Solar Cells Based on PTB7:PC<sub>71</sub>BM with Cs<sub>2</sub>CO<sub>3</sub> as a Cathode Buffer Layer
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抄録
Bulk heterojunction solar cells were fabricated using poly[[4,8-bis[(2-ethylhexyl)oxy]benzo [1,2-b:4,5-b']dithiophene-2,6-diyl] [3-fluoro-2- [(2-ethylhexyl)carbonyl]thieno[3,4-b]-thiophenediyl] (PTB7) and [6,6]-phenyl C71 butyric acid methyl ester (PC71BM) after a layer of poly(3,4- ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) was deposited on an indium tin oxide (ITO)-coated glass substrate. The fabricated structures were glass/ITO/PEDOT:PSS/PTB7:PC71BM/Cs2CO3/Al with or without the cesium carbonate (Cs2CO3) buffer layer, and the effect of the buffer layer on the performance of the solar cells was investigated. The Cs2CO3 layer with a thickness of 0.8 nm significantly increased the short circuit current density, open-circuit voltages and fill factors of the solar cells, presumably because of the better contact between the active layer and the cathode and the work function shift of the aluminum cathode. As a result, the power conversion efficiency increased from 1.09 to 2.12%. However, when thickness of the Cs2CO3 exceeded 2 nm, significant degradation was observed. From the results of a stability test, it was suggested that the inserted Cs2CO3 layer had a minimal influence on the lifetime of the unpakcaged devices.
収録刊行物
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 27 (5), 577-581, 2014
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詳細情報 詳細情報について
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- CRID
- 1390001204325710208
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- NII論文ID
- 130004691087
- 40020132939
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- NII書誌ID
- AA11576862
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- ISSN
- 13496336
- 09149244
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- NDL書誌ID
- 025604030
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可