Photochemistry of Atropisomers: Non-biaryl Atropisomers for Stereospecific Phototransformations

• Clay Anthony

  Department of Chemistry and Biochemistry, North Dakota State University

• Kumarasamy Elango

  Department of Chemistry and Biochemistry, North Dakota State University

• Ayitou Anoklase J.-L.

  Department of Chemistry and Biochemistry, North Dakota State University

• Sivaguru Jayaraman

  Department of Chemistry and Biochemistry, North Dakota State University

抄録

This review highlights the use of atropisomeric (axially chiral) chromophores for stereospecific photoreactions. The presence of axial chirality in the substrate imparts excellent stereo (enantio- and diastereo-) control affording high selectivities in point chiral photoproducts. 6π-Photocyclization and [2 + 2]-photocycloaddition are detailed as exemplars to highlight the richness and diversity of atropisomers undergoing photochemical transformations.

収録刊行物

• Chemistry Letters

  Chemistry Letters 43 (12), 1816-1825, 2014

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204588617472
• NII論文ID: 130004703969
• DOI: 10.1246/cl.140819
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/43/12/1816/55636632/cl.140819.pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可