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- Yuzuru Kobayashi
- Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba
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- Masaaki Nakamoto
- Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba
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- Akira Sekiguchi
- Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba
抄録
<jats:title>Abstract</jats:title> <jats:p>The reaction of phenyltris(trimethylsilyl)tetrahedrane with MeLi results in the formation of isolable phenylbis(trimethylsilyl)tetrahedryllithium (4a), which was characterized by X-ray crystallography and NMR spectroscopy. The derivatization of 4a via nucleophilic or cross-coupling reactions produced new tetrahedrane derivatives, including a diphenyltetrahedrane derivative with an extended π–σ–π conjugation between the σ-orbital of the tetrahedrane core and the two aryl π-systems.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 44 (2), 206-207, 2014-11-22
Oxford University Press (OUP)
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キーワード
詳細情報 詳細情報について
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- CRID
- 1360283694082327424
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- NII論文ID
- 130004712943
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- ISSN
- 13480715
- 03667022
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