Control of Open Voltage of Organic Photovoltaic Cells Using Fluorinated Self-Assembled Monolayer

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  • Mori Tatsuo
    Department of Electrical Engineering, Aichi Institute of Technology
  • Ma Xiaoling
    Department of Electrical Engineering and Computer Science, Nagoya University
  • Furuhashi Hideo
    Department of Electrical Engineering, Aichi Institute of Technology
  • Nishikawa Takao
    Center for Regional Collaboration in Research and Education, Iwate University

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Since the introduction of fluorinated self-assembled monolayer (FSAM) as a buffer layer increases the work function of indium tin oxide (ITO), it is effective for increasing in open voltage. The open voltage of organic thin-film photovoltaic cell (OPV) depends on the difference between the highest occupied molecular orbital level of donor material and the lowest unoccupied molecular orbital level of acceptor material and the work function difference between positive and negative electrodes. Consequently, it is successful to increase the open voltage using FSAM-modified ITO.

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