Reaction Parameters for the Synthesis of N,N-Dimethyl Fatty Hydrazides from Oil
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- Ahmad Norashikin
- Malaysian Palm Oil Board (MPOB), No. 6, Persiaran Institusi
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- Azizul Hasan Zafarizal Aldrin
- Malaysian Palm Oil Board (MPOB), No. 6, Persiaran Institusi
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- Hassan Hazimah Abu
- Malaysian Palm Oil Board (MPOB), No. 6, Persiaran Institusi
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- Ahmad Mansor
- Chemistry Department, Faculty of Science, University Putra Malaysia
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- Zin Wan Yunus Wan Md.
- Chemistry Department, Centre for Defence Foundation Studies, National Defence University of Malaysia
書誌事項
- タイトル別名
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- Reaction Parameters for the Synthesis of <i>N</i>,<i>N</i>-Dimethyl Fatty Hydrazides from Oil
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Hydrazide derivatives have been synthesized from methyl esters, hydrazones and vegetable oils. They are important due to their diverse applications in pharmaceutical products, detergents as well as in oil and gas industries. The chemical synthesis of fatty hydrazides is well-established; however, only a few publications described the synthesis of fatty hydrazide derivatives, particularly, when produced from refined, bleached and deodorized palm olein. Here, the synthesis and characterization of N,N-dimethyl fatty hydrazides are reported. The N,N-dimethyl fatty hydrazides was successfully synthesized from fatty hydrazides and dimethyl sulfate in the presence of potassium hydroxide with the molar ratio of 1:1:1, 6 hours reaction time and 80℃ reaction temperature in ethanol. The product yield and purity were 22% and 89%, respectively. The fatty hydrazides used were synthesized from refined, bleached and deodorized palm olein with hydrazine monohydrate at pH 12 by enzymatic route. Fourier transform infrared, gas chromatography and nuclear magnetic resonance (NMR) spectroscopy techniques were used to determine the chemical composition of N,N-dimethyl fatty hydrazides. Proton NMR confirmed the product obtained were N,N-dimethyl fatty hydrazides.
収録刊行物
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- Journal of Oleo Science
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Journal of Oleo Science 64 (1), 41-49, 2015
公益社団法人 日本油化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204091914752
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- NII論文ID
- 130004800094
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- NII書誌ID
- AA11503337
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- ISSN
- 13473352
- 13458957
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- NDL書誌ID
- 025994967
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- PubMed
- 25519290
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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