Crystal Structure of (1,10-Phenanthroline-N,N')(1,4,7,10-tetraazacyclododecane-N,N',N",N''')nickel(II) Diperchlorate

• LIN Yung-Chan

  Department of Chemistry, National Tsing Hua University

• LU Tian-Huey

  Department of Physics, National Tsing Hua University

• LIAO Fen-Ling

  Department of Chemistry, National Tsing Hua University

• CHUNG Chung-Sun

  Department of Chemistry, National Tsing Hua University

Bibliographic Information

Other Title

• Crystal Structure of (1,10-Phenanthroline-W,N′)(1,4,7,10-tetraazacyclododecane- N,N′,N″,N‴ )nickel(II) Diperchlorate

Abstract

The crystal structure of the title compound, [Ni(C₈H₂₀N₄)(C₁₂H₈N₂)](ClO₄)₂, has been determined by X-ray diffraction. The Ni(II) ion is six coordinated with four nitrogen atoms of the tetradentate macrocyclic ligand and two nitrogen atoms of the bidentate ligand in a distorted octahedron geometry. The folded tetradentate macrocyclic ligand adopts a configuration having four five-membered chelate rings in distorted eclipsed conformations. The four hydrogen atoms of the amine groups of the macrocyclic ligand are on the same side towards the bidentate ligand.

Journal

• Analytical Sciences

  Analytical Sciences 19 (6), 967-968, 2003

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390282679232527360
• NII Article ID: 130004826125
• DOI: 10.2116/analsci.19.967
• ISSN: 13482246
• ISSN: 09106340
• PubMed: 12834247
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.19.967.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.19.967/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/19/6/19_6_967/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • Crossref
  • PubMed
  • CiNii Articles
• Abstract License Flag: Disallowed