Synthesis of Triphosphatruxene via Sextuple Aromatic Nucleophilic Substitution and Simple Isolation of Stereoisomers

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  • Tatsuo Kojima
    Department of Chemistry, School of Science, The University of Tokyo
  • Shunsuke Furukawa
    Department of Chemistry, School of Science, The University of Tokyo
  • Hayato Tsuji
    Department of Chemistry, School of Science, The University of Tokyo
  • Eiichi Nakamura
    Department of Chemistry, School of Science, The University of Tokyo

抄録

<jats:title>Abstract</jats:title> <jats:p>The phosphorus analog of truxene, triphosphatruxene, was effectively synthesized by a sextuple aromatic nucleophilic substitution reaction with phenylphosphine. The vacuum sublimation process completely converted the mixture of stereoisomers into the thermodynamically unpreferred syn-isomer.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 43 (5), 676-677, 2014-01-21

    Oxford University Press (OUP)

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