Photocrosslinking of the Exterior of a Fullerene Bilayer that Prevents Vesicle Aggregation

• Koji Harano

  Department of Chemistry, The University of Tokyo

• Akimitsu Narita

  Department of Chemistry, The University of Tokyo

• Eiichi Nakamura

  Department of Chemistry, The University of Tokyo

抄録

An amphiphilic molecule bearing a coumarin moiety attached to a water-soluble fullerene via an alkyl linker forms a water-soluble fullerene bilayer vesicle in water that spontaneously agglomerates and fuses upon standing. The agglomeration–fusion ability of the vesicle was endowed probably by the intervesicular interaction between the coumarin group and the fullerene core, as judged by the lack of such ability for the vesicles bearing only alkyl groups and by complete inhibition by conversion of the coumarin group into a photodimer.

収録刊行物

• Chemistry Letters

  Chemistry Letters 43 (6), 877-879, 2014-03-15

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644035647616
• NII論文ID: 130004868198
• DOI: 10.1246/cl.140143
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/43/6/877/55641641/cl.140143.pdf
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