Anionic Polymerization of Optically Active Propene Oxides Bearing Substituted <i>N</i>,<i>N</i>-Diphenylamino Moiety

• Zhang Jin

  Key Laboratory of Environmentally Friendly Chemistry and Applications, Ministry of Education, College of Chemistry, Xiangtan University

• Zhao Chun-Hui

  Key Laboratory of Environmentally Friendly Chemistry and Applications, Ministry of Education, College of Chemistry, Xiangtan University

• Yang Li-Wen

  Key Laboratory of Environmentally Friendly Chemistry and Applications, Ministry of Education, College of Chemistry, Xiangtan University

• Yang Nian-Fa

  Key Laboratory of Environmentally Friendly Chemistry and Applications, Ministry of Education, College of Chemistry, Xiangtan University

抄録

A series of novel chiral propene oxides bearing substituted N,N-diphenylamino moiety were synthesized and anionically polymerized. Most of propene oxides gave polymers possessing high specific rotation and intensive circular dichroism (CD) signals, which were attributed to the helical conformation of the main chain. Poly(3-(4,4′-dimethoxy)diphenylaminopropene oxide) exhibited the highest specific rotation ([α ]₃₆₅²⁰ = −5400).

収録刊行物

• Chemistry Letters

  Chemistry Letters 44 (3), 250-252, 2015

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390282679563740672
• NII論文ID: 130004868385
• DOI: 10.1246/cl.141043
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/44/3/250/55643466/cl.141043.pdf
• 本文言語コード: en
• データソース種別:
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