高分子グラフトカーボンナノチューブの電気的性質

• 林田 研一

  （株）豊田中央研究所

書誌事項

タイトル別名

• Electrical Properties of Polymer-Grafted Carbon Nanotubes
• コウブンシ グラフトカーボンナノチューブ ノ デンキテキ セイシツ

抄録

Poly(cyclohexyl methacrylate)s (PCHMAs) were grafted on carbon nanotubes (CNTs) using surface-initiated polymerization technique. Electrical properties of the PCHMA-grafted CNTs (PCHMA-CNTs) were systematically measured under direct current (DC) and alternating current (AC), and compared with those of conventional nanocomposites prepared by blending PCHMA with CNT (PCHMA/CNT). At a comparable volume fraction of CNT, PCHMA-CNT is 15 orders of magnitude higher DC volume resistivity than PCHMA/CNT. This excellent electrical insulation of PCHMA-CNT is achieved by the perfect isolation of individual CNTs owing to the high molecular weight PCHMAs densely grafted on the CNTs. The highly insulated PCHMA-CNT showed the same AC frequency dependence of impedance as neat PCHMA. This means PCHMA-CNT is a dielectric. The dielectric performance of PCHMA-CNT was evaluated by comparing with that of a barium titanate-filled PCHMA composite.

収録刊行物

• 電気学会論文誌．　Ａ

  電気学会論文誌．　Ａ 135 (2), 69-74, 2015

  一般社団法人 電気学会

キーワード

• カーボンナノチューブ
• 高分子複合材料
• 誘電特性

詳細情報

• CRID: 1390001204599625088
• NII論文ID: 130004869431
• NII書誌ID: AN10136312
• DOI: 10.1541/ieejfms.135.69
• ISSN: 13475533
• ISSN: 03854205
• NDL書誌ID: 026094538
• Web Site: http://id.ndl.go.jp/bib/026094538
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I026094538
• Web Site: https://www.jstage.jst.go.jp/article/ieejfms/135/2/135_69/_pdf
• 本文言語コード: ja
• データソース種別:
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• 抄録ライセンスフラグ: 使用不可