Structure of Bis(2,2&prime;-iminodiethanol-<i>N</i>,<i>O</i>,<i>O</i>&prime;)-Nickel(II) Hydrogen-Bonded to an Organoboron Coordination Complex

• YAMAGUCHI Ryo

  Department of Material and Biological Chemistry, Faculty of Science, Yamagata University

• YAMASAKI Mikio

  X-ray Research Laboratory, Rigaku Corporation

• SAKIYAMA Hiroshi

  Department of Material and Biological Chemistry, Faculty of Science, Yamagata University

書誌事項

タイトル別名

• Structure of Bis(2,2′-iminodiethanol-<i>N</i>,<i>O</i>,<i>O</i>′)-Nickel(II) Hydrogen-Bonded to an Organoboron Coordination Complex

抄録

The nickel(II) complex [Ni{H₂(ide)}₂](BPh₄)₂·BPh(ide)·(CH₃)₂CHOH (H₂(ide) = 2,2′-iminodiethanol) was prepared, and characterized by a single-crystal X-ray method. The compound crystallizes in the triclinic space group, P1 and Z = 2, with cell parameters a = 11.8846(12)Å, b = 14.5812(11)Å, c = 20.235(2)Å, α = 73.031(5)°, β = 84.561(6)°, γ = 66.297(5)°, V = 3069.9(5)ų. In the complex cation, two H₂(ide) ligands work as tridentate ligands in the fac-forms, and the amino nitrogen atoms are at the cis-positions. The crystal contains an organoboron coordination complex, BPh(ide), and the complex cation is hydrogen-bonded to both BPh(ide) and 2-propanol molecules.

収録刊行物

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 31 (0), 19-20, 2015

  社団法人 日本分析化学会

キーワード

• Materials Chemistry
• Analytical Chemistry

詳細情報

• CRID: 1390001205301285248
• NII論文ID: 130004953668
• DOI: 10.2116/xraystruct.31.19
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/31/0/31_19/_pdf
• 本文言語コード: en
• データソース種別:
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