Highly Stereoselective Carbon–Carbon Bond-forming Reactions on Cyclopropane Rings Using 1-(Methoxycarbonyl)cyclopropylzinc Bromides

  • Sakuma Daichi
    Department of Chemistry, Faculty of Textile Science and Technology, Shinshu University
  • Yamada Kenta
    Department of Chemistry, Faculty of Textile Science and Technology, Shinshu University
  • Sasazawa Kazuya
    Department of Chemistry, Faculty of Textile Science and Technology, Shinshu University
  • Nishii Yoshinori
    Department of Chemistry, Faculty of Textile Science and Technology, Shinshu University

抄録

Highly stereoselective Reformatsky reaction and Pd-catalyzed arylation using 1-(alkoxycarbonyl)cyclopropylzinc bromide proceeded to give the trans-adduct as the major product in good to high yields with good to excellent stereoselectivities.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 44 (6), 818-820, 2015

    公益社団法人 日本化学会

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