Cross-coupling between Aryl- and Alkenyldimethylsilanes and Organic Halides Promoted by a Copper(I) Iodide/Sodium Hydride/Ethylene Glycol System

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  • Takeshi Takeda
    Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology
  • Yuichiro Takeda
    Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology
  • Akira Tsubouchi
    Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology

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<jats:title>Abstract</jats:title> <jats:p>A copper(I) iodide/sodium hydride/ethylene glycol system promoted reaction of aryl- and alkenyldimethylsilanes with C(sp3)–X electrophiles bearing a β-hydrogen produced the cross-coupling products at ambient temperature within a short period of time.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 44 (6), 809-811, 2015-03-21

    Oxford University Press (OUP)

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