An experimental study on synthesis of β-Sialon composites using fly ash and lignite char–preparation and whiskers formation
-
- ZHAO Huan
- Thermal Energy Research Centre, Shenyang Aerospace University
-
- WANG Pingyang
- Thermal Energy Research Centre, Shenyang Aerospace University
-
- YU Jianglong
- Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering, University of Science and Technology Liaoning Chemical Engineering, University of Newcastle
-
- ZHANG Jing
- Thermal Energy Research Centre, Shenyang Aerospace University
-
- TAHMASEBI Arash
- Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering, University of Science and Technology Liaoning
-
- MENG Fanrui
- Key Laboratory of Advanced Coal and Coking Technology of Liaoning Province, School of Chemical Engineering, University of Science and Technology Liaoning
書誌事項
- タイトル別名
-
- An experimental study on synthesis of β-Sialon composites using fly ash and lignite char–preparation and whiskers formation
抄録
β-Sialon based composites were produced using a vertical reactor by carbothermal reduction reaction under nitrogen using fly ash and lignite chars to examine the effects of mixing, carbon content, reaction temperature and sintering time. The influences of chars as a reductant were further investigated in comparison with graphite. The evolution of phase and morphology in samples were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM). Mechanical stirring was favored to mix fly ash and chars, while ball-milling shove the chars with porous structure due to collisions of agate balls, preventing N2 penetration to the inner parts of reactants. When excess carbon was increased to 100%, a higher combustion reactivity of low-temperature chars resulted in the production of SiC phase. The evolution of β-Sialon with increasing reaction temperature showed the samples mixed with chars were more sensitive to reaction temperature than that with graphite. β-Sialon phase increased gradually with increasing sintering time to 6 h and decreased thereafter due to the decomposition or conversion of β-Sialon. These changes were more significantly for samples adding lignite chars. The optimal operation has been determined and rod-like β-Sialon whiskers with high aspect ratio appeared after performing the operation. In the growth process of whiskers, bead-shape whiskers were observed, suggesting that the growth mechanism was different from the conventional vapor–liquid–solid (VLS) mechanism.
収録刊行物
-
- Journal of the Ceramic Society of Japan
-
Journal of the Ceramic Society of Japan 123 (1439), 542-549, 2015
公益社団法人 日本セラミックス協会
- Tweet
詳細情報
-
- CRID
- 1390001205288202112
-
- NII論文ID
- 130005085531
-
- ISSN
- 13486535
- 18820743
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可