Photo-Induced Living Radical Polymerization via Organic Catalysis

• Goto Atsushi

  Institute for Chemical Research, Kyoto University

Abstract

Photo-controlled organocatalyzed living radical polymerization was developed. The polymerization was induced and controlled at desired wavelengths over a wide range of wavelengths (350-750 nm) by exploiting suitable catalysts. This polymerization was finely responsive to the irradiation power and wavelength. The polymer molecular weight and its distribution (M_w/M_n = 1.1-1.4) were well controlled for methacrylate monomers. The monomer scope encompassed various functional methacrylates, and their block copolymers were obtained. Applicability to a wide range of polymer designs is an advantage of this polymerization.

Journal

• Journal of Photopolymer Science and Technology

  Journal of Photopolymer Science and Technology 28 (1), 37-42, 2015

  The Society of Photopolymer Science and Technology(SPST)

Keywords

• Photolysis
• living radical polymerization
• organic catalysis
• temporal control
• wavelength responsiveness

Details

• CRID: 1390282679302696704
• NII Article ID: 130005090255
• NII Article ID: 40020519424
• NII Book ID: AA11576862
• DOI: 10.2494/photopolymer.28.37
• ISSN: 13496336
• ISSN: 09149244
• NDL BIB ID: 026578697
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I026578697
• Web Site: https://www.jstage.jst.go.jp/article/photopolymer/28/1/28_37/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed