書誌事項
- タイトル別名
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- Characterization of Mixing Performance in a Microreactor and its Application to the Synthesis of Porous Coordination Polymer Particles
- マイクロリアクタ ノ コンゴウ トクセイ ヒョウカ ト タコウセイ サクタイ ビリュウシ ゴウセイ エ ノ テキヨウ
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Here we quantitatively evaluated the mixing performance of a tailor-made microreactor with central-collision type through the iodide/iodate chemical test reaction, and applied the microreactor to the synthesis of zeolitic imidazolate framework-8 (ZIF-8), which is a subclass of porous coordination polymers (PCPs) or metal organic frameworks (MOFs). The chemical test reaction demonstrated excellent mixing performance of the microreactor with a characteristic mixing time shorter than 1 millisecond, which is approximately 100 times faster than those of a batch reactor and a millimeter-sized Y-shaped mixer. Taking advantage of the rapid and uniform mixing, the microreactor successfully produced ZIF-8 particles with high reproducibility by simply mixing aqueous solutions of zinc nitrate and 2-methylimidazole. The synthesis at room temperature resulted in ZIF-8 particles with chamfered cube shape, while a lower temperature of 5℃ produced raspberry-type spherical particles. We confirmed that prepared ZIF-8 particles have BET surface area of ~1500 m2/g and exhibit the gate adsorption behavior caused by the structural transition of the ZIF-8 framework.
収録刊行物
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- 粉体工学会誌
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粉体工学会誌 52 (7), 382-389, 2015
一般社団法人 粉体工学会
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詳細情報 詳細情報について
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- CRID
- 1390001204512704256
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- NII論文ID
- 130005090548
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- NII書誌ID
- AN00222757
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- ISSN
- 18837239
- 03866157
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- NDL書誌ID
- 026608978
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可