Optical Properties of Y<sub>2</sub>Si<sub>2</sub>O<sub>7</sub>:Ce,Tb Nanoparticles Prepared by Reverse Micelle Method

  • Akino Takashi
    Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Gubarevich Anna V.
    Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Kitamoto Yoshitaka
    Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Odawara Osamu
    Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Wada Hiroyuki
    Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology

Abstract

Yttrium silicate nanoparticles were synthesized by the reverse micelle method, and their optical properties were investigated. Span 80 was used as a surfactant for the reverse micelle method. The matrix of the particles was Y2Si2O7. The particle size measured by scanning electron microscope was 10–20 nm. Photoluminescence of Y2Si2O7:Tb,Ce nanoparticles showed typical green emission from the Tb3+ ion based on transition from 5D4 to 7FJ (J = 6, 5, 4, and 3). An increase in Ce concentration increased the green emission by ultraviolet excitation because energy was transferred from the Ce3+ ion to the Tb3+ ion. The nanoparticles would be useful for various applications.

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