Designed Synthesis of Porphyrin-based Two-dimensional Covalent Organic Frameworks with Highly Ordered Structures

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  • Xiong Chen
    Department of Materials Molecular Science, Institute for Molecular Science, National Institutes of Natural Sciences
  • Jia Gao
    Department of Materials Molecular Science, Institute for Molecular Science, National Institutes of Natural Sciences
  • Donglin Jiang
    Department of Materials Molecular Science, Institute for Molecular Science, National Institutes of Natural Sciences

抄録

<jats:title>Abstract</jats:title> <jats:p>Porphyrins are representative functional π-systems; synthesizing their highly ordered structures is an established goal in chemistry. Here, we report the designed synthesis of a series of porphyrin-based covalent organic frameworks with highly ordered structures through polycondensation. The porphyrin-based frameworks exhibited high crystallinity, high porosity, and extended π-conjugation over the polyporphyrin sheets.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 44 (9), 1257-1259, 2015-06-13

    Oxford University Press (OUP)

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