Reductive Transformation of CO2 with Hydrosilanes Catalyzed by Simple Fluoride and Carbonate Salts

• Ken Motokura

  Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology

• Masaki Naijo

  Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology

• Sho Yamaguchi

  Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology

• Akimitsu Miyaji

  Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology

• Toshihide Baba

  Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology

Abstract

Hydrosilylation of CO2 catalyzed by simple fluoride and carbonate salts, such as CsF and K2CO3, is described. Total yields up to 87% for the formylated product were achieved. Mechanistic investigations indicate the reaction proceeds via the formation of an active formate species. This catalytic system was also found to be applicable to formamide synthesis from amines, CO2, and hydrosilane.

Journal

• Chemistry Letters

  Chemistry Letters 44 (9), 1217-1219, 2015-06-19

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360846644035835648
• NII Article ID: 130005096884
• DOI: 10.1246/cl.150510
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/44/9/1217/55637965/cl.150510.pdf
• Data Source:
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