Coordination Chemistry of Europium(III) Ion Towards Acylpyrazolone Ligands

• ATANASSOVA Maria

  University of Chemical Technology and Metallurgy, Department of General and Inorganic Chemistry CNRS

• KURTEVA Vanya

  Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences

• BILLARD Isabelle

  University of Grenoble Alpes CNRS

抄録

Two Eu(III) complexes were synthesized using 4-acylpyrazolone ligands: 3-methyl-4-(4-methylbenzoyl)-1-phenyl-pyrazol-5-one (HPMMBP) and 3-methyl-1-phenyl-4-(4-phenylbenzoyl)-pyrazol-5-one (HPPMBP). The composition of the obtained solid complexes was determined as Eu(PMMBP)₃·C₂H₅OH and Eu(PPMBP)₃·3H₂O based on elemental analysis and was further studied by IR, NMR and TG-TSC data. The lanthanoid complexation in solid state and in solution during liquid-liquid extraction (molecular diluent and ionic liquid) is discussed.

収録刊行物

• Analytical Sciences

  Analytical Sciences 31 (9), 917-922, 2015

  社団法人 日本分析化学会

キーワード

• Lanthanoids
• europium solid complex
• 4-acyl-5-pyrazolones
• ionic liquid

詳細情報

• CRID: 1390001204260295552
• NII論文ID: 130005097931
• NII書誌ID: AA10500785
• DOI: 10.2116/analsci.31.917
• ISSN: 13482246
• ISSN: 09106340
• NDL書誌ID: 026735710
• PubMed: 26353958
• Web Site: http://id.ndl.go.jp/bib/026735710
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I026735710
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.31.917.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.31.917/fulltext.html
• Web Site: https://www.jstage.jst.go.jp/article/analsci/31/9/31_917/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可