Relationship between the Bowl-Shaped Geometry of Phosphangulene and an Axial Group on the Phosphorus Atom

• Masaki Yamamura

• Tatsuya Nabeshima

抄録

Phosphangulene derivatives having various substituents on the phosphorus atom, which featured a bowl geometry and restrained bond angle, were synthesized in order to shed light on the relationship between the bowl geometry and the substituent. X-ray analysis revealed that the bowl geometry is significantly dependent on the axial group. An NBO analysis suggested that the bowl geometries become deep as the s-orbital character of the phosphorus orbital in the P–X bonds increases. The NMR, IR, CV, and DFT showed the large s-character in the P–X bonds of the phosphangulene lone pair.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 89 (1), 42-49, 2016-01

  Tokyo : Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1520010380541685760
• NII論文ID: 130005119451
• NII書誌ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.20150288
• NDL書誌ID: 027035469
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I027035469
• Web Site: https://academic.oup.com/bcsj/article-pdf/89/1/42/56278644/bcsj.20150288.pdf
• 本文言語コード: en
• NDL 雑誌分類:
  • ZP1(科学技術--化学・化学工業)
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