Synthesis and Crystal Structure of a Tetranuclear Mn(III)-Ni(II) Heterometal Complex of <i>N</i>-(2-oxymethylphenyl)salicylideneimine

• YOSHITAKE Megumi

  Department of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University

• YONEDA Ko

  Department of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University

• YAMADA Yasunori

  Department of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University

• KOIKAWA Masayuki

  Department of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University

抄録

A tetranuclear heterometal complex, [MnNi(L1-H)₂(OAc)]₂·2CH₃OH [H₂L1-H = N-(2-oxymethylphenyl)-salicylideneimine], was synthesized and characterized by single-crystal X-ray analysis. The compound crystallizes in a monoclinic system, spaces group P2₁/n and Z = 4 with cell parameters a = 10.638(2)Å, b = 11.483(2)Å, c = 23.538(4)Å, β = 95.505(3)°, V = 2862.1(9)ų. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0682 and 0.1200, respectively, for all 6514 independent reflections. The tetranuclear hetero-metal arrangement is represented as defected double-cubane.

収録刊行物

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 32 (0), 1-2, 2016

  社団法人 日本分析化学会

キーワード

• Materials Chemistry
• Analytical Chemistry

詳細情報

• CRID: 1390001205299421824
• NII論文ID: 130005121072
• DOI: 10.2116/xraystruct.32.1
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/32/0/32_1/_pdf
• 本文言語コード: en
• データソース種別:
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  • CiNii Articles
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