Preparation and up-conversion luminescence properties of Er<sup>3+</sup>–Yb<sup>3+</sup> co-doped CaO–WO<sub>3</sub>–SiO<sub>2</sub>–B<sub>2</sub>O<sub>3</sub>–NaF glass ceramics
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- WEI Qinlei
- School of Material Science and Engineering, Changchun University of Science and Technology
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- ZHANG Hongbo
- School of Material Science and Engineering, Changchun University of Science and Technology
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- CHEN Chen
- School of Material Science and Engineering, Changchun University of Science and Technology
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- TIAN Yingya
- School of Material Science and Engineering, Changchun University of Science and Technology
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- WEI Yanling
- School of Material Science and Engineering, Changchun University of Science and Technology
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- SONG Qiong
- School of Material Science and Engineering, Changchun University of Science and Technology
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- ZOU Xiangyu
- School of Material Science and Engineering, Changchun University of Science and Technology
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- SU Chunhui
- School of Material Science and Engineering, Changchun University of Science and Technology Changchun Normal University
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- SHAO Jing
- School of Material Science and Engineering, Changchun University of Science and Technology
書誌事項
- タイトル別名
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- Preparation and up-conversion luminescence properties of Er<sup>3+</sup>–Yb<sup>3+</sup> co-doped CaO–WO<sub>3</sub>–SiO<sub>2</sub>–B<sub>2</sub>O<sub>3</sub>–NaF glass ceramics
抄録
Er3+–Yb3+ co-doped CaO–WO3–SiO2–B2O3–NaF glass ceramics containing CaWO4 crystals were prepared by the melt-quench and crystallization method. The luminescence effect of the glass ceramic sample which was maintained for 70 min at 750°C exhibited the highest emission peak intensity in this work. As the crystallization time increased, the amount and the size of crystals increased and the crystal shape transformed from sphere to irregular polyhedron. Green and red up-conversion light appeared in the glass ceramics excited by 980 nm. Two emission peaks of green band at 525 and 545 nm correspond to 2H11/2→4I15/2 and 4S3/2→4I15/2 energy transitions of Er3+ ions and red band emission peak at 655 nm is correspond to 4F9/2→4I15/2 energy transitions of Er3+ ions. The up-conversion mechanism of Er3+–Yb3+ doped glass ceramics were investigated and the effect of excitation power on green and red light was analyzed. The up-conversion fluorescence intensity of the glass ceramics is the highest when the content of Er2O3 is 0.5 wt % and the content of Yb2O3 is 4.5 wt %.
収録刊行物
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 124 (3), 254-258, 2016
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390282680262095872
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- NII論文ID
- 130005132941
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- ISSN
- 13486535
- 18820743
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可